WebDec 4, 2024 · Biomolecular self-assembly, typically with de novo designed peptide or DNA as the building blocks, provides an effective avenue to orient and confine reactive groups into a catalytically active configuration to mimic and even rival the catalytic performance of native enzymes. In this Review, we discuss the chemical and structural properties of ... WebDNA-based hybrid catalysis. In the past decade, DNA-based hybrid catalysis has merged as a promising novel approach to homogeneous (asymmetric) catalysis. A DNA …
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WebFeb 21, 2024 · Artificial Metalloenzymes and MetalloDNAzymes in Catalysis offers a comprehensive review of the most current strategies, developed over recent decades, for the design, synthesis, and optimization... WebDouble-stranded DNA can form efficient hybrid catalysts for asymmetric catalysis upon binding of small metal complexes, which has attracted significant interest. Catalytic microenvironment... dj gana bhojpuri download 2019
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WebFeb 1, 2024 · These and other DNA hybrid catalytic systems have been shown to be “greener” methods for C-atom transfer [23,24], Lewis acid catalysis ... DNA-based hybrid catalysis. Curr. Opin. Chem. Biol., 25 (2015), pp. 80-87. Article. Download PDF View Record in Scopus Google Scholar. WebJan 8, 2015 · A DNA hybrid catalysts comprises a transition metal complex that is covalently or supramolecularly bound to DNA. The chiral microenvironment and the second coordination sphere interactions provided by the DNA are key to achieve high enantioselectivities and, often, additional rate accelerations in catalysis. WebJan 8, 2015 · In the past decade, DNA-based hybrid catalysis has merged as a promising novel approach to homogeneous (asymmetric) catalysis. A DNA hybrid catalysts comprises a transition metal complex that is covalently or supramolecularly bound to DNA. dj gana bhojpuri audio